@Controller ~ @Service

Both are different specializations of @Component annotation (in practice, they're two different implementations of the same interface) so both can be discovered by the classpath scanning (if you declare it in your XML configuration)

@Service annotation is used in your service layer and annotates classes that perform service tasks, often you don't use it but in many case you use this annotation to represent a best practice. For example, you could directly call a DAO class to persist an object to your database but this is horrible. It is pretty good to call a service class that calls a DAO. This is a good thing to perform the separation of concerns pattern.

@Controller annotation is an annotation used in Spring MVC framework (the component of Spring Framework used to implement Web Application). The @Controller annotation indicates that a particular class serves the role of a controller. The @Controller annotation acts as a stereotype for the annotated class, indicating its role. The dispatcher scans such annotated classes for mapped methods and detects @RequestMapping annotations.

So looking at the Spring MVC architecture you have a DispatcherServlet class (that you declare in your XML configuration) that represent a front controller that dispatch all the HTTP Request towards the appropriate controller classes (annotated by @Controller). This class perform the business logic (and can call the services) by its method. These classes (or its methods) are typically annotated also with @RequestMapping annotation that specify what HTTP Request is handled by the controller and by its method.

For example:

@Controller@RequestMapping("/appointments")public class AppointmentsController {    private final AppointmentBook appointmentBook;    @Autowired    public AppointmentsController(AppointmentBook appointmentBook) {        this.appointmentBook = appointmentBook;    }    @RequestMapping(method = RequestMethod.GET)    public Map<String, Appointment> get() {        return appointmentBook.getAppointmentsForToday();    }

This class is a controller.

This class handles all the HTTP Request toward "/appointments" "folder" and in particular the get method is the method called to handle all the GET HTTP Request toward the folder "/appointments".

I hope that now it is more clear for you.